The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Peroxy radicals / Alkylperoxy / C2H5O2 / Wallington(1992)_298K_215-300nm(rec)

DATAFILE: C2H5O2_Wallington(1992)_298K_215-300nm(rec).txt
NAME: ethylperoxy radical
FORMULA: C2H5O2
AUTHOR(YEAR): Wallington(1992)
T: 298K
λ: 215-300nm(rec)
BIBLIOGRAPHY: T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase", Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008
COMMENTS: Recommendation based on the data of

H. Adachi, N. Basco, and D.G.L. James, "The ethylperoxy radical spectrum and rate constant for mutual interaction measured by flash photolysis and kinetic spectroscopy," Int. J. Chem. Kinet. 11, 1211-1229 (1979),

F.C. Cattell, J. Cavanagh, R.A. Cox, and M.E. Jenkin, "A kinetics study of reactions of HO2 and C2H5O2 using diode laser absorption spectroscopy," J. Chem. Soc. Faraday Trans. II 82, 1999-2018 (1986),

C. Anastasi, D.J. Waddington, and A. Woolley, "Reactions of oxygenated radicals in the gas phase. Part 10. - Self-reactions of ethylperoxy radicals," J. Chem. Soc. Faraday Trans. I 79, 505-516 (1983), and

T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Measurements of the gas phase UV absorption spectrum of C2H5O2· radicals and of the temperature dependence of the rate constant for their self-reaction," J. Photochem. Photobiol. A: Chem. 42, 173-185 (1988)

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